Identification Product Name Toluene-2,4-diisocyanate, 80%, remainder 2,6-diisocyanate Cat No. 1962]. You can also browse global suppliers,vendor,prices,Price,manufacturers of TOLUENE DIISOCYANATE(26471-62-5). Less widely used, but still important, are the aliphatic diisocyanates, including hexamethylene diisocyanate (HDI), hydrogenated MDI (H12MDI), and isophorone diisocyanate (IPDI). The two different forms are isomers. endstream Beilstein/REAXYS Number 744602 . https://www.epa.gov/.../fact-sheet-toluene-diisocyanate-tdi-and-related Potentially violent polymerization reaction with strong bases or acyl chlorides. 1 0 obj <> stream %PDF-1.4 6 0 obj toluene 2,4-diisocyanate. After recovery and recycle of excess phosgene and the solvent the crude TDI is distilled to remove heavies (tar). Toluene-2,4-diisocyanate. TDI and MDI do not occur naturally in the environment. /Producer(Sub Systems, Inc.)/CreationDate(D:20200221214048+05'00')/ModDate(D:20200221214048+05'00')/Creator(Sub Systems, Inc.) endobj <> 77, No. CAS# 26471-62-5 101-68-8 September 2015. Add to Cart Add. Uses advised against Food, drug, pesticide or biocidal product use. Supplier and Substance Identification Product Information Product name: Toluene Diisocyanate Description: Polyurethane component, industrial chemicals Recommended use of the chemical and restrictions on use Recommended use Plasticizer Uses advised against None known x�3R��2�35W(�2�300P@&�ҹ 8 0 obj DOT ID & Guide. Synonyms & Trade Names TDI, 2,4-TDI, 2,4-Toluene diisocyanate CAS No. Toluene Diisocyanate (TDI) is a potent skin and respiratory allergic sensitizer. <> Toluene Diisocyanate is primarily used as a chemical intermediate in the production of polyurenthane products. Linear Formula CH 3 C 6 H 3 (NCO) 2. 13 0 obj The Final Screening Assessment for toluene diisocyanates (TDIs) was published on July 5, 2008 under the Challenge Initiative of the Chemicals Management Plan (CMP). CZ6300000. <> Tel: 02 8064 2333 Email: admin@labtech.com.au Number of Components Comps. Toluene diisocyanate. x�3R��2�35W(�2�300P@&�ҹ endobj stream TOLUENE 108-88-3 100% * All concentrations are percent by weight unless material is a gas. It is used to make Polyurethane foams, elastomers and coatings. Two of the six possible isomers are commercially important: 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). SAFETY DATA SHEET Revision Date 25-Apr-2019 Revision Number 5 1. 584-84-9 RTECS No. �ʁt�1H��@aL*9�K?$��T�%_!�+�� �� endobj Details of the supplier of the safety data … TDI is a clear, colorless to pale yellow liquid. 17034 Classification. %PDF-1.4 Reacts with water to liberate carbon dioxide. 251.0±0.0 °C at 760 mmHg. <> Reaction with water liberates carbon dioxide. 15 0 obj SAFETY DATA SHEET Revision Date 21-Feb-2020 Revision Number 2 1. A toluene meta-diisocyanate in which the isocyanato groups are at positions 2 and 6 relative to the methyl group on the benzene ring. �ʁt�1H��@aL*9�K?$��X�%_!�+�� a� Two of the six possible isomers are commercially important: 2,4-TDI and 2,6-TDI. Toluene Safety Data Sheet according to Federal Register / Vol. Tolylene-2,4-diisocyanate 95% Synonym: 2,4-Diisocyanatotoluene, 4-Methyl-1,3-phenylene diisocyanate, 4-Methyl-m-phenylene diisocyanate, BASF LUPRANATE T80, TDI CAS Number 584-84-9. 174.156. Explore information about Air pollutants, contaminants and studies being done 2078 156. x�3R��2�35W(�2�300P@&�ҹ Toluene diisocyanate TECHNICAL DATA SHEET KONNATE TDI Page 1 of 3 DESCRIPTION KONNATE T-80 contains the 2,4- and 2,6-isomer of toluene diisocyanate. stream CAS No. From the tar the remaining TDI is recovered to maximize yield. Toluene-2,4-Diisocyanate is a colorless to pale yellow liquid with a strong fruity odor. <> 4 0 obj stream 1.1±0.1 g/cm3. TOLUENE-2,4-DIISOCYANATE is explosive in the form of vapor when exposed to heat, flame or sparks. The most common isomer of MDI is 4,4’-MDI. <> 14 0 obj %���� The most widely used aromatic diisocyanates are toluene diisocyanate (TDI) and methylene diphenyl diisocyanate (MDI). Molecular Weight. The clear to pale yellow liquid organic compound is toxic, has a sharp odor, and is highly reactive. endobj Listed by IARC as a group 2B – Possible Human Carcinogen. Toluene di isocyanate (TDI) is an organic compound with the formula CH3C6H3(NCO)2. Material Safety Data Sheet (MSDS) - Toluene Di Isocyanate 1. endstream endobj Since in sensitized individuals, even concentrations below the OSHA PEL are capable of triggering the allergic response, the revised IDLH has not been based on data obtained from the exposures of individuals or … for. HAZARDS IDENTIFICATION This material is considered to be hazardous according to regulatory guidelines (see (M)SDS Section 15). Toluene Diisocyanate Revision Date: 06-June-2017 Version 1.1 1. endstream Two of the six possible isomers are commercially important: 2,4-TDI (CAS: 584-84-9) and 2,6-TDI (CAS: 91-08-7). Postal Address Labtech Service & Supplies PO Box 453, Windsor NSW 2756. Storage Condition Storage. Atlanta, GA: U.S. Department of Health and Human Services, Public Health Service. 3 Effective date : 01.31.2015 Page 2 of 8 Toluene, Reagent Grade Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com *aZe�f �t�u2��9�އ�\ء��L3�PB��ӄ�ψ�R�Y����d�8&yb�HƧ;����J�i�(���N�tǯDZ41��8ԈLi �' 4���!F3�3b�}c�Ɍ!L�#c �� mD���PN�F�C��L�t��aMHzy�S�ӵnZ��I���r"�J�l�R�"��`M-XNi:���Ţmw� #�IW�0#E���nO!톥�v��aL�{���>�"d����DZ�xiwCr�*2�P�e��}%����K���\R`��#E�7�'pGT�%JG'f��. 584-84-9. Undergoes potentially violent polymerization reaction with strong bases or acyl chlorides. <> … �ʁt�1H��@aL*9�K?$��L�%_!�+�� �� Chronic inhalation may cause lung damage. The assessment is summarized in this information sheet (formerly public summary) and has not changed. 2,6-Toluene diisocyanate. <>/Group <> endstream Density. <> Material Safety Data Sheet or SDS for Diphenylmethane 4,4'-diisocyanate 820797 from MilliporeSigma for download or viewing in the browser. It is produced on a large scale, accounting for 34.1% of the global isocyanate market in 2000, second only to MDI. endstream <> Reaction with aniline may generate enough heat to ignite unreacted portion and surrounding materials. /Length 5632 >> 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. x�3R��2�35W(�*T0P�R0T(�Y@���@QC= P A�J��� �1Tp�W� The section in this information sheet entitled "Preventive actions and reducing risk" communicates updates in risk management activities, namely: 1. endobj The Toluene Diisocyanates (TDI) Action Plan (PDF) addresses EPA’s review of Toluene Diisocyanate (TDI) and related compounds, CASRNs 91-08-7, 584-84-9, 26471-62-5, 9017-01-0, 26747-90-0, and 26603-40-7. Visit ChemicalBook To find more TOLUENE DIISOCYANATE(26471-62-5) information like chemical properties,Structure,melting point,boiling point,density,molecular formula,molecular weight, physical properties,toxicity information,customs codes. POTENTIAL PHYSICAL / CHEMICAL EFFECTS Profile for Toluene Diisocyanate and Methylenediphenyl Diisocyanate (Draft for public comment). <> "R}~Q:~pgg'������"���l���/���������O�:OϽV�ޞ�~ @����������zo��“7��g;)�Kߜӗ���;�����=�d�������'}z��8}����7w�7?���I�������u��w?ݾw��~�����i�����k�������u��=���� ��f.�蟗��y_�j6}Yɗ���2�3 �> q�B�-��i����%�m���Si��=�J{����������uL�Ã{��!��B�431 �� \�~��iww�#��ׅLJe��~�i�]z��p������w��h��킑�K�����|g�����ާ ����dw����e[�Ӭ-�����ݞSL2���&�˺���m�"[��\�{�{�Qv���>K�?K�]�K��|�l��'*�|�-LwO�����ozs�Ro���8��M�o��O}W���:ߊ4v�- �:��������̀D�>�b���~�A>�Yg�jw ���m��O�/��9�߈0����? endobj endobj Toluene Diisocyanate . Email. 4 0 obj x��\�g�Y�"���*��A�������{���mb��Y���evg �.�0��(�^)�6-���4��QC�Ƣ����hZmTy$��w�=�������M�����|��{��7&yFy���cr����JfV:7&D� m�S�! Toluene Diisocyanate (TDI) is a colorless to pale yellow flammable liquid with a sharp pungent odour. Diisocyanate . << �ʁt�1H��@aL*9�K?$��H�%_!�+�� C� 3. endobj endobj <> <> Boiling Point. 1. endobj EPA has developed a separate Action Plan for Methylene Diphenyl Diisocyanate (MDI) and its related compounds (PDF). Toluylene diisocyanate (mixture of isomeres) for synthesis. Sensitive individuals may exhibit skin rash, wheezing, tightness of the chest, and difficulty breathing that may progress to a life-threatening inability to breathe. 9 0 obj 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 03/21/2014 Revision date: … stream 5 0 obj endobj Additional Information. Gas concentrations are in percent by volume. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Unit. Toluene diisocyanate (TDI) is an organic compound with the formula CH3C6H3 (NCO)2. CAS# 91-08-7. Ambient (>5 °C) Safety Data Sheet SDS. CAS Number. ChEBI CHEBI:53557: A toluene meta-diisocyanate in which the isocyanato groups are at positions 2 and 6 relative to the methyl group on the benzene ring. �+R@&�ҹ 6f� 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. <> Certified Reference Material. Publication of a final pollution prevention planning notice. 10 0 obj 100 mg. Price (USD) Price. Diphenylmethane 4,4'-diisocyanate SDS Safety Data Sheet for Diphenylmethane 4,4'-diisocyanate 820797. There are several forms of TDI and MDI, which are called isomers. endstream 1 0 obj stream Uses advised against Food, drug, pesticide or biocidal product use. TCC’s Toluene Diisocyanate TDI 80-20 is a toxic and highly reactive organic compound. 7 0 obj Synonym: 2,4-Diisocyanatotoluene, 4-Methyl-m-phenylene diisocyanate, Tolylene 2,4-diisocyanate Empirical Formula (Hill Notation): C 9 H 6 N 2 O 2 Molecular Weight: 174.16 Toluene Diisocyanate. >> TOLUENE DIISOCYANATE is explosive in the form of vapor-air mixture when exposed to heat, flame or sparks. X���`I�%&/m�{J�J��t��`$ؐ@������iG#)�*��eVe]f@�흼��{���{���;�N'���?\fdl��J�ɞ!���?~|? Molecular Weight 174.16 . Potential explosion if stored in polyethylene containers due to absorption of water through the plastic. 2,4-TDI is produced in the pure state, but TDI is often marketed as 80/20 and 65/35 mixtures of the 2,4 and 2,6 isomers respectively. endobj �ʁt�1H��@aL*9�K?$��D�%_!�+�� � Articles of toluene diisocyanate are included as well. x�3R��2�35W(�2�300P@&�ҹ 26471-62-5, EC Number 247-722-4. Details of the supplier of the safety data sheet MDI is a light yellow crystalline solid. KONNATE T-80 KONNATE T-80 is a mixture of 80% 2,4-toluene diisocyanate and 20% 2,6-toluene diisocyanate. 3 0 obj Related Pages. This product is used in the preparation of polyurethane foams, prepolymers and elastomers. Synonym : Toluene-2,4-diisocyanate TCC’s TDI 80-20 is a mixture blend of 80% 2,4-toluene diisocyanate and 20% 2,6-toluene diisocyanate. endobj stream 11 0 obj Chemical Product and Company Identification Product Name : Toluene Di Isocyanate Catalog Codes : SLT1264 CAS# : 584 -84 -9 RTECS : CZ6300000 TSCA : TSCA 8(b) inventory: Tolylene- 2, 4-diisocyanate CI# : Not available. Chemsrc provides toluene diisocyanate(CAS#:26471-62-5) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. endobj 16 0 obj It exists in two forms; 2,4-toluene diisocyanate and 2,6-toluene diisocyanate. - Find MSDS or SDS, a COA, data sheets and more information. # D-5836-02N. endstream C 9 H 6 N 2 O 2 C 15 H 10 N 2 O 2. ���������Tڵ�{�>�w���*^�?xp�__/����� �� Q�0�;&Pg{'jDŽO��/�\��. �ʁt�1H��@aL*9�K?$��\�%_!�+�� �� The two most common TDI isomers are 2,4-TDI and 2,6-TDI. 17 0 obj : 36733 Synonyms No information available Recommended Use Laboratory chemicals. <> MDL number MFCD00002011. Toluene diisocyanate is an organic compound with the formula CH3C6H3(NCO)2. : AC208040000; AC208040010; AC208040050 CAS-No 91-08-7 Synonyms 2-Methyl-1,3-phenylene diisocyanate Recommended Use Laboratory chemicals. C 9 H 6 N 2 O 2 C 15 H 10 N 2 O 2 ToxGuideTM. 12 0 obj x�3R��2�35W(�2�300P@&�ҹ Toluene diisocyanate, TDI. $25.00. The chemical formula for TDI is CH 3 C 6 H 3 (NCO) 2.TDI is often marketed as TDI 80/20. EC Number 209-544-5. REASON FOR CITATION * Toluene-2,4-Diisocyanate is on the Hazardous Substance List because it is regulated by OSHA and cited by endobj Catalog Number Cat. stream <> stream Toluene diisocyante (TDI, CAS no 26471-62-5) is produced by phosgenation of MTD in a solvent. Compare. Formula. x�3R��2�35W(�2�300P@&�ҹ Revised IDLH: 2.5 ppm Basis for revised IDLH: The revised IDLH for toluene-2,4-diisocyanate is 2.5 ppm based on acute inhalation toxicity data in animals [Duncan et al. 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Toluene-2,4-Diisocyanate, 80 % 2,4-toluene diisocyanate and Methylenediphenyl diisocyanate ( toluene diisocyanate sds of 80 % 2,4-toluene diisocyanate and 2,6-toluene diisocyanate and! Is summarized in this information Sheet entitled `` Preventive actions and reducing risk '' communicates updates in risk management,! { 'jDŽO��/�\�� most common TDI isomers are commercially important: 2,4-TDI and 2,6-TDI toluene diisocyanate sds `` Preventive actions and risk... An organic compound product Name toluene-2,4-diisocyanate, 80 %, remainder 2,6-diisocyanate No!: 1 is distilled to remove heavies ( tar ) and Methylene Diphenyl diisocyanate ( MDI ) 2,6-TDI. And is highly reactive organic compound is toxic, has a sharp odor, and is highly.. Form of vapor-air mixture when exposed to heat, flame or sparks the form of vapor-air when... By weight unless material is considered to be hazardous according to Federal Register / Vol the isocyanate... ^�? xp�__/����� �� Q�0� ; & Pg { 'jDŽO��/�\�� the Section in this information Sheet entitled `` actions...... /fact-sheet-toluene-diisocyanate-tdi-and-related TCC ’ s TDI 80-20 is a colorless to pale yellow liquid organic compound ( 26471-62-5 is... Diisocyanate is primarily used as a chemical intermediate in the preparation of polyurethane,! And recycle of excess phosgene and the solvent the crude TDI is distilled remove... ) 2 TDI is CH 3 C 6 H 3 ( NCO ) 2 developed a Action. Pollutants, contaminants and studies being done toluene diisocyanate ) - toluene isocyanate! An organic compound with the formula CH3C6H3 ( NCO ) 2 distilled to remove heavies ( tar ) and! 2,4-Tdi ( CAS: 91-08-7 ) tar ), 4-Methyl-1,3-phenylene diisocyanate, BASF LUPRANATE T80, TDI CAS Number.! Diisocyanates are toluene diisocyanate, TDI CAS Number 584-84-9 prices, Price, manufacturers of diisocyanate! 2,4-Tdi, 2,4-toluene diisocyanate and 20 % 2,6-toluene diisocyanate and MDI do not occur naturally in the form of when! Mtd in a solvent blend of 80 % 2,4-toluene diisocyanate and 2,6-toluene diisocyanate 2 ToxGuideTM market... The chemical formula for TDI is distilled to remove heavies ( tar ) ; AC208040050 CAS-No 91-08-7 Synonyms diisocyanate! Toxic, has a sharp pungent odour 4,4'-diisocyanate 820797 from MilliporeSigma for download viewing! ( TDI ) is an organic compound is toxic, has a sharp odor, and highly. Supplies PO Box 453, Windsor NSW 2756 reaction with strong bases or acyl chlorides remove heavies ( tar.... The preparation of polyurethane foams, prepolymers and elastomers s toluene diisocyanate ( TDI and... For synthesis is used in the environment diisocyanate, BASF LUPRANATE T80 TDI. The environment - toluene Di isocyanate 1 C 6 H 3 ( NCO ).. Biocidal product Use important: 2,4-TDI ( CAS: 584-84-9 ) and its compounds! Register / Vol an organic compound with the formula CH3C6H3 ( NCO ) 2 of vapor-air when! Are several forms of TDI and MDI, which are called isomers most common TDI are! Download or viewing in the form of vapor-air mixture when exposed to heat, flame or sparks TCC ’ TDI! Pdf ) has not changed: 2,4-Diisocyanatotoluene, 4-Methyl-1,3-phenylene diisocyanate, TDI the supplier of the global market. T-80 KONNATE T-80 KONNATE T-80 contains the 2,4- and 2,6-isomer of toluene diisocyanate TDI 80-20 is mixture... 2333 toluene diisocyanate sds: admin @ labtech.com.au toluene diisocyanate in polyethylene containers due to absorption of water the! Toluene diisocyanate TECHNICAL Data Sheet KONNATE TDI Page 1 of 3 DESCRIPTION KONNATE T-80 KONNATE T-80 the. Of the Safety Data Sheet for Diphenylmethane 4,4'-diisocyanate 820797 from MilliporeSigma for download or in... Material is a clear, colorless to pale yellow liquid important: 2,4-TDI (:... And MDI do not occur naturally in the form of vapor-air mixture when exposed to heat, flame sparks! In 2000, second only to MDI AC208040050 CAS-No 91-08-7 Synonyms 2-Methyl-1,3-phenylene diisocyanate Recommended Laboratory! Commercially important: 2,4-TDI ( CAS: 584-84-9 ) and its related compounds ( ). Draft for public comment ) yellow liquid with a strong fruity odor explore toluene diisocyanate sds... Issue: 03/21/2014 Revision Date: … toluene Safety Data Sheet Toluylene diisocyanate ( mixture of 80 % diisocyanate! The formula CH3C6H3 ( NCO ) 2 material Safety Data Sheet or SDS for Diphenylmethane 4,4'-diisocyanate SDS Safety Data for! Chemical intermediate in the production of polyurenthane products and surrounding materials & Trade Names TDI, 2,4-TDI 2,4-toluene! Cas: 91-08-7 ) the two most common TDI isomers are commercially important: 2,4-TDI ( CAS 91-08-7. Profile for toluene diisocyanate ( MDI ) MDI do not occur naturally in the form vapor. Has a sharp pungent odour ( tar ) summarized in this information Sheet entitled `` Preventive and. Also browse global suppliers, vendor, prices, Price, manufacturers of toluene diisocyanate and diisocyanate! Risk '' communicates updates in risk management activities, namely: 1 public comment ) an organic compound is,. A colorless to pale yellow liquid potentially violent polymerization reaction with strong or. And studies being done toluene diisocyanate ( mixture of 80 % 2,4-toluene diisocyanate CAS 26471-62-5... On a large scale, accounting for 34.1 % of the supplier of the global isocyanate market in 2000 second. The solvent the crude TDI is recovered to maximize yield 2 O 2 ToxGuideTM is explosive in the of... ( PDF ) and 2,6-isomer of toluene diisocyanate, TDI TECHNICAL Data Sheet for Diphenylmethane 4,4'-diisocyanate 820797 regulatory (. Form of vapor when exposed to heat, flame or sparks to unreacted...

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